Tuesday, October 13, 2015

Antheropogenic Impacts of Fertilizers on Environment




INTRODUCTION
Fertilizer is a substance added to soil to improve plants' growth and yield. First used by ancient farmers, fertilizer technology developed significantly as the chemical needs of growing plants were discovered. Modern synthetic fertilizers are composed mainly of nitrogen, phosphorous, and potassium compounds with secondary nutrients added. The use of synthetic fertilizers has significantly improved the quality and quantity of the food available today, although their long-term use is debated by environmentalists.
Like all living organisms, plants are made up of cells. Within these cells occur numerous metabolic chemical reactions that are responsible for growth and reproduction. Since plants do not eat food like animals, they depend on nutrients in the soil to provide the basic chemicals for these metabolic reactions. The supply of these components in soil is limited, however, and as plants are harvested, it dwindles, causing a reduction in the quality and yield of plants.
Fertilizers replace the chemical components that are taken from the soil by growing plants. However, they are also designed to improve the growing potential of soil, and fertilizers can create a better growing environment than natural soil. They can also be tailored to suit the type of crop that is being grown. Typically, fertilizers are composed of nitrogen, phosphorus, and potassium compounds. They also contain trace elements that improve the growth of plants.
The primary components in fertilizers are nutrients which are vital for plant growth. Plants use nitrogen in the synthesis of proteins, nucleic acids, and hormones. When plants are nitrogen deficient, they are marked by reduced growth and yellowing of leaves. Plants also need phosphorus, a component of nucleic acids, phospholipids, and several proteins. It is also necessary to provide the energy to drive metabolic chemical reactions. Without enough phosphorus, plant growth is reduced. Potassium is another major substance that plants get from the soil. It is used in protein synthesis and other key plant processes. Yellowing, spots of dead tissue, and weak stems and roots are all indicative of plants that lack enough potassium.
Calcium, magnesium, and sulfur are also important materials in plant growth. They are only included in fertilizers in small amounts, however, since most soils naturally contain enough of these components. Other materials are needed in relatively small amounts for plant growth. These micronutrients include iron, chlorine, copper, manganese, zinc, molybdenum, and boron, which primarily function as cofactors in enzymatic reactions. While they may be present in small amounts, these compounds are no less important to growth, and without them plants can die.
Many different substances are used to provide the essential nutrients needed for an effective fertilizer. These compounds can be mined or isolated from naturally occurring sources. Examples include sodium nitrate, seaweed, bones, guano, potash, and phosphate rock. Compounds can also be chemically synthesized from basic raw materials. These would include such things as ammonia, urea, nitric acid, and ammonium phosphate. Since these compounds exist in a number of physical states, fertilizers can be sold as solids, liquids, or slurries.


HISTORY
The process of adding substances to soil to improve its growing capacity was developed in the early days of agriculture. Ancient farmers knew that the first yields on a plot of land were much better than those of subsequent years. This caused them to move to new, uncultivated areas, which again showed the same pattern of reduced yields over time. Eventually it was discovered that plant growth on a plot of land could be improved by spreading animal manure throughout the soil.
Over time, fertilizer technology became more refined. New substances that improved the growth of plants were discovered. The Egyptians are known to have added ashes from burned weeds to soil. Ancient Greek and Roman writings indicate that various animal excrements were used, depending on the type of soil or plant grown. It was also known by this time that growing leguminous plants on plots prior to growing wheat was beneficial. Other types of materials added include sea-shells, clay, vegetable waste, waste from different manufacturing processes, and other assorted trash.
Organized research into fertilizer technology began in the early seventeenth century. Early scientists such as Francis Bacon and Johann Glauber describe the beneficial effects of the addition of saltpeter to soil. Glauber developed the first complete mineral fertilizer, which was a mixture of saltpeter, lime, phosphoric acid, nitrogen, and potash. As scientific chemical theories developed, the chemical needs of plants were discovered, which led to improved fertilizer compositions. Organic chemist Justus von Liebig demonstrated that plants need mineral elements such as nitrogen and phosphorous in order to grow. The chemical fertilizer industry could be said to have its beginnings with a patent issued to Sir John Lawes, which outlined a method for producing a form of phosphate that was an effective fertilizer. The synthetic fertilizer industry experienced significant growth after the First World War, when facilities that had produced ammonia and synthetic nitrates for explosives were converted to the production of nitrogen-based fertilizers.

TYPES OF CHEMICAL FERTILIZERS

The different types of chemical fertilizers are usually classified according to the three principal elements, namely Nitrogen (N), Phosphorous (P) and Potassium (K), and may, therefore, be included in more than one group.
Nitrogenous Fertilizer Types
This type of fertilizer is divided into different groups according to the manner in which the Nitrogen combines with other elements. These groups are:
Ammonium Sulphate
This fertilizer type comes in a white crystalline salt form, containing 20 to 21% ammonia cal nitrogen. This fertilizer type is soluble in water; its nitrogen is not readily lost in drainage, because the ammonium ion is retained by the soil particles. A note of caution: Ammonium sulphate may have an acid effect on garden soil. Over time, the long-continued use of this type of fertilizer will increase soil acidity and thus lower the yield. The application of Ammonium sulphate fertilizer can be done before sowing, at sowing time, or even as a top-dressing to the growing crop.
Ammonium Nitrate
This fertilizer type also comes in white crystalline salts. Ammonium Nitrate salts contains 33 to 35% nitrogen, of which half is nitrate nitrogen and the other half in the ammonium form. As part of the ammonium form, this type of fertilizer cannot be easily leached from the soil. This fertilizer is quick-acting, but highly hygroscopic thus making it unfit for storage. On a note of caution: Ammonium Nitrate also has an acid effect on the soil.
Ammonium Sulphate Nitrate
This fertilizer type is available as a mixture of ammonium nitrate and ammonium sulphate and is recognizable as a white crystal or as dirty-white granules.  Ammonium Sulphate Nitrate is non-explosive, readily soluble in water and is very quick-acting. Because this type of fertilizer keeps well, it is very useful for all crops. Though it can also render garden soil acidic, the acidifying effects is only one-half of that of ammonium sulphate on garden soil. Application of this fertilizer type can be done before sowing, at sowing time or as a top-dressing, but it should not be applied along the seed.
Urea
This type of fertilizer usually is available to the public in a white, crystalline, organic form. It is a highly concentrated nitrogenous fertilizer and fairly hygroscopic. Urea is also produced in granular or pellet forms and is coated with a non-hygroscopic inert material. It is highly soluble in water and therefore, subject to rapid leaching. It is, however, quick-acting and produces quick results. When applied to the soil, its nitrogen is rapidly changed into ammonia. Application of Urea as fertilizer can be done at sowing time or as a top-dressing, but should not be allowed to come into contact with the seed.
Ammonia
This fertilizer type is a gas that is made up of about 80% of nitrogen and comes in a liquid form Ammonia can be applied by introducing it into irrigation water, or directly into the soil from special containers. Use of ammonia as a fertilizer is very expensive.
Phosphate Fertilizer Types
The Phosphate fertilizers are categorized as natural phosphates, either treated or processed, and also by products of phosphates and chemical phosphates.
Rock Phosphate
As a type of fertilizer, rock phosphate occurs as natural deposits in some countries. Powdered phosphate fertilizer is an excellent remedy for soils that are acidic and has a phosphorous deficiency and requires soil amendments. However, the disadvantage is that although phosphate fertilizer such as rock phosphate contains 25 to 35% phosphoric acid, the phosphorous is insoluble in water. It has to be pulverized to be used as a type of fertilizer before rendering satisfactory results in garden soil.
Super phosphate
Super phosphate is a fertilizer type that most gardeners are familiar with. As a fertilizer type one can get super phosphate in three different grades, depending on the manufacturing process. The following is a short description of the different super phosphate fertilizer grades:
·         Single super phosphate containing 16 to 20% phosphoric acid;
  • Dicalcium phosphate containing 35 to 38% phosphoric acid; and
  • Triple super phosphate containing 44 to 49% phosphoric acid.
Triple super phosphate is used mostly in the manufacture of concentrated mixed fertilizer types. All garden soil types can benefit from the application of Super phosphate as a fertilizer. Used in conjunction with an organic fertilizer, it should be applied at sowing or transplant time.
Bone-meal
 Bone-meal is used as a phosphate fertilizer type and is available in two types: raw and steamed. The raw bone-meal contains 4% organic Nitrogen that is slow acting, and 20 to 25% phosphoric acid that is not soluble in water. The steamed bone-meal on the other hand has all the fats, greases, nitrogen and glue-making substances removed as a result of high pressure steaming. But it is more brittle and can be ground into a powder form. In powder form this fertilizer is of great advantage to the gardener in that the rate of availability of the phosphoric acid depends on its pulverization. This fertilizer is particularly suitable as a soil amendment for acid soil and should be applied either at sowing time or even a few days prior to sowing.

Potassium fertilizer types
Chemical Potassium fertilizer should only be added when there is absolute certainty that there is a Potassium deficiency in your garden soil. Potassium fertilizers also work well in sandy garden soil that responds to their application. Crops such as chilies, potato and fruit trees all benefit from this type of fertilizer since it improves the quality and appearance of the produce. There are basically two different types of potassium fertilizers:
  • Muriate of potash (Potassium chloride) and
  • Sulphate of potash (Potassium sulphate).
Muriate of Potash
Muriate of potash is a gray crystal type of fertilizer that consists of 50 to 60% potash. All the potash in this fertilizer type is readily available to plants because it is highly soluble in water. Even so, it does not leach away deep into the soil since the potash is absorbed on the colloidal surfaces.
Sulphate of Potash
Sulphate of potash is a fertilizer type manufactured when potassium chloride is treated with magnesium sulphate. It dissolves readily in water and can be applied to the garden soil at any time up to sowing. Some gardeners prefer using sulphate of potash over muriate of potash.

Organic fertilizers ('natural' fertilizer)



Naturally occurring organic fertilizers include manure, worm castings, peat moss, seaweed, sewage and guano. Sewage sludge use in organic agricultural operations in the U.S. has been extremely limited and rare due to USDA prohibition of the practice (due to toxic metal accumulation, among other factors)
Cover crops may are also grown to enrich soil as a green manure through nitrogen fixation from the atmosphere by bacterial nodules on roots); as well as phosphorus (through nutrient mobilization) content of soils.
Processed organic fertilizers from natural sources include compost (from green waste), blood meal and bone meal(from organic meat production facilities), and seaweed extracts (alginates and others).

Mixed definitions of 'organic'

There can be confusion as to the veracity of the term 'organic' when applied to agricultural systems and fertilizer. The problem is one of confusion of terminology between agricultural and chemical disciplines.
Minerals such as mined rock phosphate, sulfate of potash and limestone are also considered organic fertilizers, although they contain no organic (carbon) molecules. Some ambiguity in the usage of the term organic exists; however, it is simple to differentiate with a separation between the scientific and colloquial uses
Synthetic fertilizers, such as urea and urea formaldehyde, are organic in the sense of the organic chemistry definition of organic, can be supplied organically (agriculturally), but when manufactured as a pure chemical is not organic under organic certification standards.
Naturally mined powdered limestone, mined rock phosphate and sodium nitrate, are inorganic (in a chemical sense) in that they contain no carbon molecules, and are energetically-intensive to harvest, but are approved for organic agriculture in minimal amounts.

Benefits of organic fertilizer

However, by their nature, organic fertilizers provide increased physical and biological storage mechanisms to soils, mitigating risks of over-fertilization. Organic fertilizer nutrient content, solubility, and nutrient release rates are typically much lower than mineral (inorganic) fertilizers. One study found that over a 140-day period,
  • Organic fertilizers had released between 25% and 60% of their nitrogen content
  • Controlled release fertilizers(CRFs) had a relatively constant rate of release
  • Soluble fertilizer released most of its nitrogen content at the first leaching

Disadvantages of organic fertilizer

It is difficult to chemically distinguish between urea of biological origin and those produced synthetically. It is possible to over-apply organic fertilizers.

ENVIRONMENTAL IMPACTS OF FERTILIZERS

Fertilizers contribute to the variety, abundance, and low cost of food stuffs available to the public. However, fertilizer misuse can lower air, soil, and water quality.

Impacts of Intensive Farming on Soil and Water Resources:

Damage to Soil:
Soil erosion from farmland threatens the productivity of agricultural fields and causes a number of problems elsewhere in the environment. Agricultural topsoil takes up to 300 years for 1 inch to form, soil that is lost is essentially irreplaceable. The amount of erosion varies considerably from one field to another, depending on soil type, slope of the field, drainage patterns, and crop management practices; and the effects of the erosion vary also. Areas with deep organic loams are better able to sustain erosion without loss of productivity than are areas where topsoils are shallower.
·         Erosion affects productivity because it removes the surface soils, containing most of the organic matter, plant nutrients, and fine soil particles, which help to retain water and nutrients in the root zone where they are available to plants.
·         The effects of erosion are also felt elsewhere in the environment. A recent study estimated the off-site cost of cropland erosion in the United States to be in the range of a billion dollars per year (Clark, Haverkamp, and Chapman 1985).
·         The eroded soils contain nutrients and other chemicals that are beneficial on farm fields, but can impair water quality when carried away by erosion. As a result, drinking water supplies may contain nitrate or organic chemicals in concentrations that exceed public health standards or surface waters may become clogged with excessive plant growth from the added nutrients.
·         Even when soil erosion is not excessive, intensive agriculture can impair soil quality by depleting the natural supplies of trace elements and organic matter.
Contamination of Water:
·         Farming is one potential source of such contamination. Surface runoff carries manure, fertilizers, and pesticides into streams, lakes, and reservoirs, in some cases causing unacceptable levels of bacteria, nutrients, or synthetic organic compounds.
·         Similarly, water percolating downward through farm fields carries with it dissolved chemicals, which can include nitrate fertilizers and soluble pesticides. In sufficient quantities these can contaminate groundwater supplies.
·         Eroded soil clogs streams, rivers, lakes, and reservoirs, resulting in increased flooding, decreased reservoir capacity, and destruction of habitats for many species of fish and other aquatic life.
·         Nutrients are lost from agricultural fields through runoff, drainage, or attachment to eroded soil particles. The amounts lost depend on the soil type and organic matter content, the climate, slope of the land, and depth to groundwater, as well as on the amount and type of fertilizer and irrigation used.
·         Leaching of nitrate from agricultural fields can elevate concentrations in underlying groundwater to levels unacceptable for drinking water quality. In the Suffolk County area of Long Island, for example, almost 10 percent of private wells tested for nitrate exceed the 10 mg/l drinking water standard.
·         Phosphorus is carried with eroded soil into surface water bodies where it may cause excessive growth of aquatic plants. If this process precedes far enough, lakes and reservoirs become choked with decaying mats of algae, which have offensive odors and can cause fish kills from the resulting lack of dissolved oxygen.

Eutrophication:

The most complete global study of eutrophication was the Organization for Economic Cooperation and Development (OECD) Cooperative Programme on Eutrophication carried out in the 1970s.Although both nitrogen and phosphorus contributes to eutrophication. The symptoms and impacts of eutrophication are:

  • Increase in production and biomass of phytoplankton, attached algae, and macrophytes.
·         Production of toxins by certain algae.
·         Increasing operating expenses of public water supplies, including taste and odour problems, especially during periods of algal blooms.
·         Deoxygenation of water, especially after collapse of algal blooms, usually resulting in fish kills.
·         Infilling and clogging of irrigation canals with aquatic weeds.
·         Economic loss due to change in fish species, fish kills, etc.

Problems with Organic fertilizers

Major problems are associated with organic fertilizers. Manure produced by cattle, pigs and poultry are used as organic fertilizer the world over. Intensive livestock production has produced major problems of environmental degradation in the Eastern and Southern parts of the Netherlands.
· Surface waters and the groundwater are being contaminated by heavy metals. High concentrations of these substances pose a threat to the health of man and animals. To a certain extent these heavy metals accumulate in the soil, from which they are taken up by crops. For example, pig manure contains significant quantities of copper.
· Acidification as a result of ammonia emission (volatilization) from livestock accommodation, manure storage facilities, and manure being spread on the land. Ammonia constitutes a major contribution to the acidification of the environment, especially in areas with considerable intensive livestock farming.

Environmental Implications of Fertilizer Mismanagement:

When nutrients and other pollutants associated with animal manures and commercial fertilizers are not managed properly, they can affect plant and animal life (including humans) negatively. Some of these impacts include algae blooms causing the depletion of oxygen in surface waters, pathogens and nitrates in drinking water, and the emission of odors and gases into the air.

Oxygen depletion:

When manure or commercial fertilizers enter surface water, the nutrients they release stimulate microorganism growth. The growth and reproduction of these microorganisms will reduce the dissolved oxygen content of the water body.
Without sufficient dissolved oxygen in surface water, fish and other aquatic species suffocate. The resulting dead fish degrade the water quality and cause unpleasant odors.

Weed growth and algae blooms:

The number of plants and algae in a lake, pond or other water body increase with an increased supply of nutrients, particularly nitrogen (N) and phosphorus (P). The nutrient present in the least amount for growth will limit the production in the aquatic system. However, increased production of aquatic plants and algae is not healthy for water resources. For example, 1 extra pound of P in a lake can produce hundreds of pounds of weeds and algae that compete with other aquatics for oxygen. Eutrophication is the term used to describe the natural or human accelerated process whereby a water body becomes abundant in aquatic plants and low in oxygen content.
Health effects:
In addition to oxygen depletion, there is potential that the algae can be toxic. Blue-green algae (cyano-bacteria) can cause rashes, nausea and respiratory problems in humans and has been documented to kill livestock that drink from affected water storage.
Ammonia toxicity:
Ammonia-contaminated runoff from fresh manure application sites is toxic to aquatic life. At high enough levels, ammonia in surface water will kill fish. Fish are relatively sensitive to ammonia in water. Concentrations as low as 0.02 parts per million (ppm) may be lethal.

Fecal organisms:
The fresh manure from warm-blooded animals has countless microorganisms, including bacteria, viruses, parasites and fungi. Some of the organisms are pathogenic (disease causing).If manure applications are mismanaged near wells, the risk of bacterial contamination of the groundwater via the well is greatly increased. Therefore, avoid surface application of manure where it can come into direct contact with a well or other drinking water supply.

Nitrates in drinking water:

High levels of nitrates in drinking water are known to cause methemoglobinemia (blue-baby syndrome) in human infants and other warm-blooded animals. In human infants, the nitrate is ingested, usually in water used to mix formula, and nitrate-reducing bacteria in the upper gastrointestinal system convert it to nitrite. The nitrite, in turn, interferes with the uptake and movement of oxygen throughout the body. The pale, bluish color of the infant's skin is the result of oxygen deprivation.

Odors and gases:
Manure odors can be a nuisance for nearby neighbors and communities. Constant nuisance odors can degrade the "quality of life" for anyone.
Gases are emitted from facilities throughout the year, but are released at the highest rates during agitation, pumping and application of liquid manure systems or during cleanout and application of solid manure systems. Volatilization of ammonia to the atmosphere may become a water quality problem near animal production facilities when it is returned to the earth dissolved in rainfall. (http://www.ag.ndsu.edu/pubs)

Global Ethical Issues
The growth of the world's population to its current figure has only been possible through intensification of agriculture associated with the use of fertilizers. There is an impact on the sustainable consumption of other global resources as a consequence.
The use of fertilizers on a global scale emits significant quantities of greenhouse gas into the atmosphere. Emissions come about through the use of:

·   animal manures and urea, which release methane, nitrous oxide, ammonia, and carbon dioxide in varying quantities depending on their form (solid or liquid) and management (collection, storage, spreading)
·   fertilizers that use nitric acid or ammonium bicarbonate, the production and application of which results in emissions of nitrogen oxides, nitrous oxide, ammonia and carbon dioxide into the atmosphere.

By changing processes and procedures, it is possible to mitigate some, but not all, of these effects on anthropogenic climate change.
The nitrogen-rich compounds found in fertilizer run-off are the primary cause of a serious depletion of oxygen in many parts of the ocean, especially in coastal zones; the resulting lack of dissolved oxygen is greatly reducing the ability of these areas to sustain oceanic fauna.

 Fertilizing Alternatives

Fertilizers contain nitrogen, phosphorous, potassium, and other elements that help build strong roots and plants.  But as the saying goes, too much of a good thing can be bad. 
Many of us unknowingly waste time and money by putting too much of the wrong kind of fertilizer on our landscapes, often at the wrong times.  This is partially because our soil is not properly balanced (that is, it’s too acidic or alkaline) to allow plants to absorb the nutrients they need in the first place.  Not only does your lawn and wallet suffer, but so does the environment.
Generally speaking, lawns need much less fertilizer than is advertised.  Fertilizers that are not immediately absorbed by plants in our landscapes end up polluting our water through storm water runoff.  These excess nutrients either leach through the soil to the groundwater or they are washed by rain into storm drains that lead to the nearest water body.  These nutrients can contaminate our drinking water and cause rapid alga growth in ponds and bays.  Alga blooms not only make swimming and boating unpleasant, but also block sunlight and deplete oxygen, killing fish and other animals.  
Save time and money by following these helpful guidelines to provide your lawn with all the nutrients it needs to be healthy, beautiful, and easy to maintain.

Add lime if your soil is acidic:
Soil’s pH should be between 6.0 and 7.0 for a healthy lawn.  Most landowners will find that their soil’s pH is below 7, which means it is acidic.  Acidic soil is more hospitable to weeds than grass because it prevents nutrient absorption.  Adding lime will remedy this problem. To raise your soil’s pH one point, use a mechanical spreader to evenly broadcast 40 pounds of palletized lime per 1000 square feet of grass.

Leave grass clippings on the lawn:
Mulching mowers create fine grass clippings that will break down and add nitrogen and organic matter to the soil.  Leaving grass clippings on the lawn over the season provides the equivalent of one regular fertilizer application, and will not cause thatch.  Take advantage of this free natural fertilizer and let nature do the work!

Top dress with compost:
If soil analysis shows that lawn needs nutrients, a thin layer of compost (1/4” or less) will provide most of what your soil needs.  Compost also adds organic materials that help the soil retain moisture. The best time to treat your lawn with compost is in the spring, by using a wheelbarrow, shovel and lawn rake.

If necessary, use organic fertilizers.  For this, be sure to: (1) use an organic, slow-release, water-insoluble fertilizer at the recommended dose; (2) don’t spread the fertilizer if heavy rain is predicted; and (3) evenly distribute the fertilizer using a mechanical spreader at the lowest setting, going over the area two or three times.

Organic fertilizers and synthetic fertilizers are not the same.
Organic fertilizers are less concentrated, but have longer lasting benefits because they gradually release nutrients.  Synthetic fertilizers are more concentrated which makes it is easier to over fertilize, burning the plant, and potentially harming soil organisms.  Synthetic fertilizers also tend to be more water-soluble, leaching out of the soil faster and potentially polluting our water resources. Organic fertilizers offer an additional benefit of recycling waste that would otherwise contribute to pollution.


Alternative Fertilizer Choices Including Organic Options



Conventional fertilizer is made mainly from phosphorus, a natural element already found in most soils. Though, phosphorous is natural and already in soil, adding additional phosphorus to soil is usually unnecessary and sometimes even harmful to the environment. In many cases, people put far too much fertilizer on their lawns. The excess phosphorous disrupts their garden’s natural ecosystem balance. Causing certain plants to swell and dominate unnaturally just like plants on steroids.
Organic lawn care compared to contemporary intensive lawn care is much healthier for the yard the environment and in many cases to one’s family. There are almost an infinite number of fertilizer variations that can be used to supply the nutrients recommended by your soil test.  The following information will help to fine tune fertilizer program or make substitutions.

Alternatives for 10:10:10 (N/P/K):

1 lb. of 10-10-10
                        Equals 5 lbs. of dried, aged chicken manure
                        Equals 10 lbs. of composted cow manure
                        Equals 30-40 lbs. of fresh horse and cow manure
                        Equals 2 lbs. of fishmeal

Nitrogen alternatives

3 lbs. of ammonium nitrate OR
2 lbs. of urea OR
5 lbs. of ammonium sulfate
                        Equals 8 lbs. of blood meal
                        Equals 13 lbs. of soybean extract

Potash alternatives

1 lb. of, muriate of potash
                        Equals 2 lbs. of potassium sulfate
                        Equals 7 lbs. of green compost

Phosphate alternatives
1 lb. of super treble phosphate
                        Equals 4 lbs. of steamed bone meal
                        Equals 2 lbs. of rock phosphate
Natural organic materials are variable in nutrient content from different samples, therefore, the quantities listed above are approximate. 

References:
·         (http://www.fao.org/docrep

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